دانلود کتاب باتری‌های سدیم یونی – مواد و فناوری های ذخیره انرژی

Excessive exploitation and use of fossil fuels have caused rapid reduction of the natural resources and a series of environmental issues such as extreme weather and greenhouse effect. With the awakened public awareness of the finiteness of the earth’s resources, the renewable energy sources (e.g. solar, wind, tide, etc.) are developed as alternatives. While the intermittent character of these energy sources calls for more efficient energy storage systems. Over the past 30 years, lithium-ion batteries (LIBs) technology has advanced with unparalleled progress and is now dominating the market in portable electronic devices and electric vehicles. While with dwindled reserves of the raw materials, a rise in LIB price is foreseen. Sodium-ion batteries (SIBs) share similar electrochemistry and fabrication technologies to LIBs while featuring with low cost and better safety due to earthabundant sodium resources, rendering them a promising alternative to LIBs in large-scale energy storage. Over the past years, a wealth of research works has been dedicated to the development and commercialization of SIBs. There has been gratifying progress achieved and on other hand, urged greater efforts are still needed to address the unresolved troubling issues. This book intends to provide researchers and graduate/undergraduate students in related fields of materials science and electrochemistry with a snapshot of current efforts in improving the SIB technology, as well as pave the way for the development of a new generation of higher-energy density, rechargeable SIBs through comprehensive optimization in electrode materials, electrolytes, and other key components. Chapters 1 and 2 provide a basic introduction (including history, operation principle, key materials, etc.) to SIBs, as well as outline some design principles in terms of energy density, power density, cycling life, and safety to build highperformance SIBs. Chapters 3 to 6 systematically introduce the cathode materials of transition metal oxides, polyanionic compounds, Prussian blue analogues, and organic compounds for SIBs, in terms of structural design, electrochemical properties, and the corresponding reaction mechanisms. From Chapter 7 to Chapter 10, intercalation-type anode materials (carbon-based materials, titanium-based materials, etc.), alloy- and conversion-type anode materials (metals/metal alloys, metal oxides/metal chalcogenides, phosphorous/phosphides, etc.), and Na metal anodes are described. Electrolytes including organic liquid electrolytes, ionic liquid electrolytes, and solid electrolytes are mentioned in Chapters 11 to 13. Besides, binder is also an important part of SIBs, and its progress is summarized in Chapter 14. For practical applications, three types of sodium-ion full batteries (SIFBs) including non-aqueous, aqueous, and all-solid-state SIFBs are discussed in Chapter 15. And, the last Chapter 16 gives perspectives on the opportunities and potential benefits of SIBs for large-scale energy storage. Finally, I gratefully acknowledge the substantial contribution from Prof. Yanglong Hou, Prof. Xiaogang Zhang, Prof. Xianhong Rui, Prof. Hongfa Xiang, Dr. Lina Zhao, Prof. Yuan-Li Ding, Prof. Changbao Zhu, Prof. Laifa Shen, Prof. Jianmin Ma, Prof. Feixiang Wu, Prof. Xuyong Feng, Dr. Dan Yang, Dr. Xianghua Zhang, and Dr. Wei Luo to this book.