دانلود کتاب فناوری‌های پایدار زیست‌محیطی، جلد 2

Due to the continuous occurrence of water pollution problems, practical separation methods for oil–water mixtures have attracted more and more attention. To date, different kinds of materials have been developed with good hydrophobic properties and strong separation ability. Carbon aerogels, as a promising ideal adsorbent for dealing with oil-spill accidents, have received extensive attention. In this work, zeolitic imidazolate frameworks (ZIFs), nanoparticles, and carbon nanotubes (CNTs) in the three-dimensional (3D) interconnected network structure of cotton balls (CBs) were successfully prepared by a simple and scalable process. The as-prepared carbonized CBs with carbonized ZIF-8 and CNTs (CZIF-8/CNTs/CCBs) were characterized. The oil–water separation performance of the composite was also measured. The results show that the ZIF-8 clusters intercalated with abundant CNTs are fully loaded into the porous structure of the CBs after the in situ synthesis process. Additionally, ZIF-8/CNTs/CBs was carbonized in nitrogen, leading to the formation of CZIF-8/CNTs/CCBs. The prepared material possesses excellent hydrophobicity with a water contact angle of 152.7◦, showing good absorption capacities Q1 in the range of 48 to 84 times its original weight for oil and organic liquids. In addition, CZIF-8/CNTs/CCBs exhibits good recyclability in the absorption–distillation test. In summary, this study proposes a novel and simple method for the preparation of a superhydrophobic material that could have wide application in the separation of oil–water mixtures.